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The effect of substituents on the reactivity of dichloridotriphenylphosphinoruthenium(II) complexes: kinetic and mechanistic study.
(Journal of Coordination Chemistry, 2021-03-24)
The rates of substitution of chloro ligands from a series of ruthenium(II) complexes, [Ru(κ3-L)(PPh3)Cl2] (L = 2,2′:6′,2′′-terpyridine, 1; 4′-(4-methylphenyl)-2,2′:6′,2′′-terpyridine, 2; 4,4′4″-tri-tert-butyl-2,2′:6′,2′′ ...
Degradation characteristics of metribuzin in soils within the Nzoia River Drainage Basin, Kenya
(Toxicological and Environmental Chemistry, 2015-12-31)
Metribuzin, a triazinone herbicide, is heavily used within the expansive Nzoia River Drainage Basin in Kenya for the optimization of sugarcane yields. For field experiments, soils were spiked with metribuzin and amended ...
Role of pore chemistry and topology in the heavy metal sorption by zeolites: From molecular simulation to machine learnin
(Computational Materials Science, 2021-04-23)
Zeolite frameworks can provide pores that enable selective heavy metals sorption, making these materials promising for energy-efficient heavy metals capture. In the present study, the adsorption of hazardous heavy metal ...
Computational screening of zeolites for the adsorption of selected pharmaceutical pollutants
(SN Applied Sciences, 2020-10-27)
Molecular simulations have been used as a screening tool to identify promising zeolites for the removal of selected pharmaceutical pollutants. 40 zeolites with different structural and chemical configurations were studied. ...
The effect of substituents on the reactivity of dichloridotriphenylphosphinoruthenium(II) complexes: kinetic and mechanistic study
(JOURNAL OF COORDINATION CHEMISTRY, 2021-03-24)
The rates of substitution of chloro ligands from a series of ruthenium(II) complexes, [Ru(κ3-L)(PPh3)Cl2] (L = 2,2′:6′,2′′-terpyridine, 1; 4′-(4-methylphenyl)-2,2′:6′,2′′-terpyridine, 2; 4,4′4″-tri-tert-butyl-2,2′:6′,2′′ ...
The influence of α,α′-diimine bridging ligand on the reactivity of binuclear para-cymene ruthenium(II) complexes. Kinetic, mechanistic and computational study
(Inorganica Chimica Acta journal, 2021-01)
Substitution kinetics of the aqua ligands in four binuclear ruthenium(II) para-cymene complexes with different α,α′-diimine bridging ligands [2-pyridylaldazine (Ru-1), p-phenylenebis(picoline)aldimine (Ru-2), p-biphenyle ...
Role of pore chemistry and topology in the heavy metal sorption by zeolites: From molecular simulation to machine learning.
(Science Direct, 2021-07)
Zeolite frameworks can provide pores that enable selective heavy metals sorption, making these materials promising for energy-efficient heavy metals capture. In the present study, the adsorption of hazardous heavy metal ...
The role of N,N-chelate ligand on the reactivity of (?(6)-p-cymene)Ru(II) complexes: kinetics, DNA and protein interaction studies.
(ournal of Coordination Chemistry, 2019-09-20)
This study reports the kinetic studies of aqua complexes (Ru1–Ru6) as well as the calf-thymus DNA (CT-DNA) and bovine serum albumin binding studies of their chloro derivatives (Ru7–Ru11). The rate of substitution of the ...
Chlorpyrifos Degradation in Soils with Different Treatment Regimes Within Nzoia River Drainage Basin, Kenya
(Bulletin of Environmental Contamination and Toxicology, 2015-03-24)
Two organic amendments, filter mud compost and Tithonia diversifolia leaves generated within a sugarcane growing area were used to enhance the degradation of chlorpyrifos in soil. Filter mud compost and T. diversifolia ...